1, 1-binaphthyl-based Chiral Materials: Our Journey

Chiral materials have been studied in the Department of Chemistry at the University of Virginia for applications in areas like asymmetric catalysis, enantioselective fluorescent sensing, and optical/electrical materials. Optically active 1,1 -binaphthyl molecules are used to build novel chiral polymers, dendrimers, macrocycles, and acyclic molecules. 1,1 -Binaphthyl molecules are chosen because of their remarkably stable chiral configuration as well as their high asymmetric inductions in many processes. In this book, both the fundamental knowledge about the 1,1 -binaphthyl molecules and the synthesis of the structurally diverse 1,1 -binaphthyl-based materials are described. The applications of these materials in various fields are also discussed. This book will serve as a reference for graduate students as well as other professionals working in the related fields. Introduction About 1,1 -Binaphthyls Main Chain Chiral-Conjugated Polymers Polybinaphthyls in Asymmetric Catalysis Asymmetric Catalysis by BINOL and Its Non-Polymeric Derivatives Enantioselective Fluorescent Sensors Based on 1,1 -Binaphthyl Derived Dendrimers, Small Molecules and Macrocycles Miscellaneous Studies on Materials Related to 1,1 -Binaphthyls